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  <record>
    <language>eng</language>
    
      <publisher>Oriental Scientific Publishing Company</publisher>
    
    <journalTitle>Material Science Research India</journalTitle>
    
      <issn>0973-3469</issn>
    
    
    <publicationDate>2017-06-25</publicationDate>
    

        <volume>14</volume>

        <issue>1</issue>

 

    <startPage>31</startPage>
    <endPage>36</endPage>

   
      <doi></doi>
    
    <publisherRecordId>5379</publisherRecordId>
    <documentType>article</documentType>
    <title language="eng">A Study of Supported Poly(N-Butyl Methacrylate) (Pbma) Thin Polymer Films Near The Glass Transition Temperature</title>

    <authors>
	 


      <author>
       <name>Rami A. Omari</name>

 
		

	<affiliationId>1</affiliationId>
      </author>
    


	 


      <author>
       <name>Gilbert Ayuk</name>


		

	<affiliationId>2</affiliationId>

      </author>
    


	


	



	



	

    </authors>
    
	    <affiliationsList>
	    
		

		<affiliationName affiliationId="1">Department of physics, Al al-Bayt University, P.O.BOX 130040, Mafraq 25113, Jordan.</affiliationName>
    


		

		<affiliationName affiliationId="2">Fulton-Montgomery Community College, 2805 State Highway 67, Johnstown, NY 12095 .</affiliationName>
    

		

		

		

		

	  </affiliationsList>







    <abstract language="eng">The glass transition temperature and the surface dynamics of poly (butyl methacrylate) (PBMA) films have been studied using a phase-modulated ellipsometer equipped with a home-built sample cell with temperature controller. Experiments were performed for a range of temperatures, both above and below the glass transition temperature (Tg). In our study the glass transition temperature was obtained by plotting the ellipticity,  as a function of temperature using the data from the ellipsometric cooling scan. the correlation functions governing the fluctuations were calculated  at each temperature from the time-dependent fluctuations in film thickness as a function of temperature using ellipsometry data collected at 50 Hz frequency.  The results indicate that at temperatures well above Tg, the correlation functions obey a simple exponential decay. However, as Tg is approached, the correlation functions are best fitted with a stretched exponential relation, indicating a broad distribution of relaxation times. In addition, the temperature dependence of surface relaxation process has been found to be much weaker compared to the bulk relaxation.</abstract>

    <fullTextUrl format="html">https://www.materialsciencejournal.org/vol14no1/a-study-of-supported-polyn-butyl-methacrylate-pbma-thin-polymer-films-near-the-glass-transition-temperature/</fullTextUrl>




      <keywords language="eng">
        <keyword>Correlation function</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Ellipsometer</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Glass transition temperature</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Stretched exponential relation</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Thin polymer films</keyword>
      </keywords>


      <keywords language="eng">
        <keyword></keyword>
      </keywords>

  </record>

</records>