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  <record>
    <language>eng</language>
    
      <publisher>Oriental Scientific Publishing Company</publisher>
    
    <journalTitle>Material Science Research India</journalTitle>
    
      <issn>0973-3469</issn>
    
    
    <publicationDate>2017-12-25</publicationDate>
    

        <volume>14</volume>

        <issue>2</issue>

 

    <startPage>140</startPage>
    <endPage>145</endPage>

   
      <doi></doi>
    
    <publisherRecordId>5842</publisherRecordId>
    <documentType>article</documentType>
    <title language="eng">Upconversion and Spectroscopic Properties of Rare Earth Codoped Lead Borate Glass Matrix</title>

    <authors>
	 


      <author>
       <name>K Krishna Murthy Goud</name>

 
		

	<affiliationId>1</affiliationId>
      </author>
    


	 


      <author>
       <name>Ch Ramesh</name>


		

	<affiliationId>2</affiliationId>

      </author>
    


	 


      <author>
       <name>B Appa Rao</name>

		

	<affiliationId>3</affiliationId>
      </author>
    


	



	



	

    </authors>
    
	    <affiliationsList>
	    
		

		<affiliationName affiliationId="1">Dept. of Physics, UCE (A), Osmania University, Hyderabad-500007 (T.S), India.</affiliationName>
    


		

		<affiliationName affiliationId="2">Dept. of Physics, M G University, Nalgonda (T.S), India.</affiliationName>
    

		

		<affiliationName affiliationId="3">Dept. of Physics, Osmania University, Hyderabad-500007 (T.S), India.</affiliationName>
    

		

		

		

	  </affiliationsList>







    <abstract language="eng"><p>To develop efficient upconversion laser materials in the visible region an active lead borate glasses doped with Er<sup>3+</sup>/Yb<sup>3+</sup>  rare earth ions (GEY) has been studied extensively. In this investigation characterization techniques like Optical absorption, FTIR and photoluminescence were recorded and the data was analyzed. To evaluate the values of Ω<sub>2</sub>, Ω<sub>4</sub> and Ω<sub>6</sub> Judd-Ofelt theory has been applied to the f ↔ f transitions. Based on Judd–Ofelt theory branching ratio (<i>β<sub>r</sub></i>) oscillator strength and the radiative life time (<i>τ<sub>R</sub></i>) values were determined. The upconversion spectra exhibited three emission bands at around 525 nm (<sup>2</sup>H<sub>11/2 </sub>® <sup>4</sup>I<sub>15/2</sub>), 545 nm (<sup>4</sup>S<sub>3/2 </sub>® <sup>4</sup>I<sub>15/2</sub>) and 660 nm (<sup>4</sup>F<sub>9/2 </sub>® <sup>4</sup>I<sub>15/2</sub>). The energy transfer mechanism between Yb<sup>3+</sup> and Er<sup>3+</sup> was discussed very clearly. Comparing the data obtained in other Er<sup>3+</sup>/Yb<sup>3+ </sup>doped materials, the lead bismuth gallium borate glasses doped with 0.6 mol% of Er<sub>2</sub>O<sub>3­</sub>/0.2 mol% of Yb<sub>2</sub>O<sub>3</sub> ions are suitable materials for developing red upconversion lasers in the visible region.</p></abstract>

    <fullTextUrl format="html">https://www.materialsciencejournal.org/vol14no2/frequency-upconversion-in-er3yb3-codoped-lead-bismuth-gallium-borate-glasses/</fullTextUrl>




      <keywords language="eng">
        <keyword>FTIR</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Glasses</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Optical absorption</keyword>
      </keywords>


      <keywords language="eng">
        <keyword> Photo luminescence</keyword>
      </keywords>

  </record>

</records>