A compound CuNiTiO4 is prepared by Solid diffusion method in the laboratory using standard chemical crystallographic of CuNiTiO4 is done using XRD. The Electrical properties are studied under which the variation of electrical conductivity with respect to temperature is obtained and type of charge carriers is determine electrical resistivity of the sample can be measured with dc or ac method. In the present work dc method is used, using LCR meter for the resistivity measurements.