Chemiluminescence of Lucigenin has been studied in aqueous amine solutions. The Chemiluminescence emission spectra are recorded using a Fuess spectrograph. A broad emission band appears in the visible region from 470 to 640 nm having an emission peak of 550 nm at the concentration of 1 ? 10-3 M lucigenin. The resolved Chemiluminescence emission band show three peaks having maxima at 510, 555 and 610 nm respectively. The mechanism of Chemiluminescence of Lucigenin is based on Chemiluminescence, fluorescence and absorption of lucigenin in aqueous methyl and ethyl amines.