Ultrasonic and Transport Studies of Molecular Interactions in Ternary Organic Liquid Mixtures at 303, 308 and 313K


R. Palani*1, R. Kesavasamy2 and M. Akila1

*1Department of Physics, D.D.E., Annamalai University, Annamalainagar - 608 002 (India). 

2Department of Physics, Sri Ramakrishna Engineering College, Coimbatore - 641 022 (India).

DOI : http://dx.doi.org/10.13005/msri/050215

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ABSTRACT:

Density (r), viscosity (h) and ultrasonic velocity (U) measurements have been carried out in three ternary liquid mixtures of chlorobenzene, nitrobenzene and bromobenzene with acetophenone and 1-propanol mixtures at 303, 308, 313K. From the experimental measurements, the acoustical parameters such as adiabatic compressibility (b), free volume (Vf), and Gibb?s free energy (DG) have been calculated. The excess value of the above parameters and Grunberg-Nissan interaction parameter (d) have also been computed and discussed in the light of molecular interaction in the mixtures.

KEYWORDS:

Ultrasonic velocity; compressibility; Gibb?s free energy; interaction parameter

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Article Publishing History
Received on: 12 Feb 2008
Accepted on: 4 Apr 2008


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ISSN

Print: 0973-3469, Online: 2394-0565


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