Electrical Transport Study of Superionic System Li3po4 : X Li3vo4


Rajesh Kumar Patel, Satyendra Singh and Kanchan Gaur

Department of Physics, K.N. Government P.G. College, Gyanpur, Bhadohi (India).

DOI : http://dx.doi.org/10.13005/msri/040221

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ABSTRACT:

Measurement of electrical conductivity (s) and Seebeck coefficient (S) have been performed on the solidified melt of the lithium based superionic system Li3PO4 : x Li3VO4 where x = 0.0, 0.33, 0.50, 0.67, 1.0, 1.5 and 2.0 in the temperature range 500 K to the melting point of the materials. All the studied materials are purely ionic in superionic phase which has been observed below their melting point. At phase transition solids undergo from normal to superionic phase. Ionic and electronic parts of electrical conductivity have also been separated. These solids are mixed conductors in normal phase. Electrical conduction mechanism have also been discussed..

KEYWORDS:

Electrical transport; superionic system; electrical conductivity; seebeck coefficient

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Article Publishing History
Received on: 16 Oct 2007
Accepted on: 15 Dec 2007


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ISSN

Print: 0973-3469, Online: 2394-0565


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