Studies of Electrochemical Behavior of Composite Electrode ?[Co-(Ortophenontroline) 3] 2+ + Graphite? in Aqueous and THF Media


Z. Modarress Tehrani1* and J. Mofidi2

1Department of Chemistry, Al-Zahra University, Vanak Street, Tehran (Iran)

2Islamic Azad University, North Tehran branch, Faculty of Chemistry, Tehran (Iran)

DOI : http://dx.doi.org/10.13005/msri/040110

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ABSTRACT:

In this research, we were interest to study the electrochemical behaviour of modified composite electrode" [Co-Ph3]2+, 2ClO4-complex? mixed with ?graphite powder?, at different per cent weights and pressures in aqueous and THF media. According to our results in aqueous solution, 0.1M NaClO4, one irreversible system CoII/CoI (DEp @ 250 mv) and in ?THF + TBAP 0.1M, two irreversible systems CoII/ CoII and CoII/CoIand appear and the later is more irreversible. The main idea is to verify electro-catalytic assis

KEYWORDS:

composite electrode; cyclic voltammetry; 110-orthophenantroline- Co (II) complex

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Article Publishing History
Received on: 13 May 2007
Accepted on: 20 Jun 2007


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ISSN

Print: 0973-3469, Online: 2394-0565


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